TCPP, CAS#13674-84-5

TCPP

Tris(2-chlorisopropyl) Phosphate;

CAS No.: 13674-84-5
EC No.: 237-158-7
Molecular Formula:C9H18Cl3O4P

O TCPP é um retardante de chama organofosforado (OPFR) clorado, insolúvel em água e com boa estabilidade.

Trata-se de um éster de fosfato que combina fósforo (cerca de 9,5%) e cloro (cerca de 32,5%), por isso tem excelentes propriedades retardantes de chama e plastificantes para produtos de poliuretano, plástico e borracha.

Sua solubilidade em água é de 1,6 g/L a 20 °C, sendo insolúvel em hidrocarbonetos alifáticos, porém solúvel em benzeno, álcool, éster, tetracloreto de carbono e outros solventes orgânicos.
Durante o armazenamento, o TCPP deve ser vedado e protegido da umidade.

A seguir, o texto original em inglês.
The following is the original English text.

Synonyms:
TCIPP; TCIP; TMCP;
Tris(Chloropropyl) Phosphate;
2-Propanol,1-chloro-,phosphate (3:1);
2-Propanol,1-chloro-, 2,2′,2”-phosphate;
Tris(2-chloro-1-methylethyl) phosphate;
PROPAN-2-OL, 1-CHLORO-, PHOSPHATE; トリス(βークロロプロピル)ホスフェート TCPP

Other CAS Number:
1244733-77-4;
Phosphoric trichloride, reaction products with propylene oxide;
Reaction products of phosphoryl trichloride and 2-methyloxirane;

TCPP is an chlorinated(hologen) OrganoPhosphorus Flame Retardant (OPFR) which is insoluble in water and has good stability.

TCPP is a phosphate ester combining phosphorus (about 9.5%) and chlorine (about 32.5%), so it has excellent flame retardant and plasticizing properties for polyurethane, plastic and rubber products.

It’s solubility in water 1.6g/L at 20℃, insoluble in aliphatic hydrocarbons, soluble in benzene, alcohol, ester, carbon tetrachloride and other organic solvents.
TCPP should be sealed and protected from moisture in storage.

Uses:
TCPP is especially recommended used in PIR / PUR foams, e.g. polyurethane insulation foams, structural foams and low-density flexible foams.
TCPP can be used in flexible and rigid polyurethane foam (PUR), polyvinylchloride (PVC), epoxy resin, polyester, thermosets, polyisocyanurate foam (PIR), adhesive, etc.
The dosage of TCPP is about 10% to 20%, please adjust the dosage according to the formula and specific use.

Technical data:
Appearance: colorless or light yellow transparent liquid
Acid value (mg KOH/g): ≤0.1
Refractive index: 1.4620-1.4650
Viscosity(25°C,mpa.s): 60–70
Specific gravity(25°C, g/cm3): 1.28-1.30
Chromaticity(APHA): ≤50
Moisture: ≤0.1%
Phosphorus content: 9.4%±0.4%
Chlorine
content: 32.5%±0.5%

Package:
250kg per Drum; 1250kg per IBC; about 25 tonnes isotank; Flexitank;
Store in a dry, shaded, cool, well-ventilated area, sealed and protected from moisture.

Related Flame Retardants (FRs)

>>Halogen-free Aromatic PolyPhosphate FRs:
RDP BDP
For Engineering plastics (e.g. PC/ABS alloys, PC, ABS, modified PPE), etc.
>>Halogenated Chlorinated Phosphate FRs:
TCPP TDCPP
For Polyurethanes (e.g. flexible and rigid PUR foams), etc.
>>Melamine-based nitrogen FRs:
Melamine Cyanurate -MCA
Melamine Phosphate -MP
Melamine PolyPhosphate -MPP

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